By A. K. Bhowmick, M. Bhattacharya, S. Mitra, K. Dinesh Kumar (auth.), Gert Heinrich (eds.)
Morphology–Property courting in Rubber-Based Nanocomposites: a few fresh advancements, via A. ok. Bhowmick, M. Bhattacharya, S. Mitra, okay. Dinesh Kumar, P. okay. Maji, A. Choudhury, J. J. George and G. C. Basak; * Rubber–Clay Nanocomposites: a few contemporary effects, by means of Amit Das, De-Yi Wang, Klaus Werner Stöckelhuber, René Jurk, Juliane Fritzsche, Manfred Klüppel and Gert Heinrich; * floor amendment of Fillers and Curatives by way of Plasma Polymerization for superior functionality of unmarried Rubbers and diverse Rubber/Rubber Blends, by means of J. W. M. Noordermeer, R. N. Datta, W. okay. Dierkes, R. Guo, T. Mathew, A. G. Talma, M. Tiwari and W. van Ooij; * fresh advancements on Thermoplastic Elastomers through Dynamic Vulcanization, by means of R. Rajesh Babu and Kinsuk Naskar; * PTFE-Based Rubber Composites for Tribological purposes, by way of M. S. Khan and G. Heinrich
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The storage modulus values of nanoclay-loaded sample are higher in the entire frequency range in comparison with the unfilled sample. This suggests the reinforcing action of nanoclay in the BIMS matrix. The effect of nanoclay reinforcement on the important molecular parameters of elastomers, such as relaxation times (terminal relaxation time, tte and onset of transition zone relaxation time, ttr) and monomer friction coefficient (z0), have been estimated from the different crossover frequencies (as shown in Fig.
The dependence of rheological properties on the nanocomposite morphology has also been reported in the literature [96, 97]. Kim et al. reported that use of o-MMT in NBR resulted in an increase in Mooney viscosity and torque values . The rheological behavior of o-MMT-filled NR/ENR blend Morphology–Property Relationship in Rubber-Based Nanocomposites 21 nanocomposite systems was investigated through Mooney viscosity measurements . It has been observed that the viscosity of NR blend nanocomposites increases slightly with the incorporation of the organoclay (5 phr).
As the rubber–filler interaction increases, the available free-chains decrease, resulting in a decrease in tan dmax. The lowest value of tan dmax in FNA4-V is due to better filler dispersion and higher interaction between the fluoroelastomer and polar unmodified clay compared to the organically modified clay. This observation has been found to be very unique for the fluoroelastomer nanocomposite system. Over a wide range of temperatures, both the unmodifiedand the modified-clay-filled systems show increased storage modulus compared to the gum vulcanizate (Fig.