Advances in Catalysis and Related Subjects, Volume 4 by W G Frankenberg

By W G Frankenberg

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Am. Petroleum Znst. 27 [III],23 (1947). 31. Matheson, G. , Proc. Am. Petroleum Znst. 27 [111], 18 (1947). 32. , Advances in Catalysis, 3, 250 (1951). 33. Ritter, H. , and Drake, L. , Znd. Eng. , Anal. Ed. 17, 782 (1945). 34. Drake, L. , Znd. Eng. Chem. 41, 780 (1949). 35. Tamele, M. , Faraday Soc. Discussion 8, 270 (1950). 36. Mills, G. , Boedeker, E. , and Oblad, A. , J . Am. Chem. Soc. 72,1554 (1950). 37. , J . Chem. 2164 (1948). 38. , J . Am. Chem. 72, 1164 (1950). 39. Milliken, T. , Mills, G.

Paw 31 35 1. , . . . . . . . . . . . 2. Reduction of Halogens by Hydrogen Peroxide.. . . . . . . . . . . 3. The Steady State . . . . . . . . . . . . . . . . . . . . . . . . 36 37 37 ..................... 43 2. Active Intermediates. . . . . . . . . . . . . . . . . . . . . . . . . 62 VI. Copper Compounds.. . . . . . . . . . . . . . 71 VII. ,. . . . . . . 75 I. INTRODUCTION It is a measure of the complexity and variety of the chemical reactions in which hydrogen peroxide participates that they have attracted the attention of chemical kineticists for almost a hundred years, and that many of the earliest reactions to be investigated still provide matter for further investigations.

Of these reactions the group involving the catalytic decomposition to water and oxygen by various agents has 31 32 J. H. BAXENDALE probably been studied most extensively. Such agents are numerous and varied and include some elements and elementary ions-metallic and nonmetallic, more complex ions such as coordination compounds and ions derived from oxyacids, enzymes, and many materials in the solid and colloidal state. We shall be concerned here with the catalytic decomposition in true aqueous solution, and the catalysts which are active in this state are in the main inorganic compounds.

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