Advances in heterocyclic chemistry. 112 by Alan R. Katritzky

By Alan R. Katritzky

Confirmed in 1960, Advances in Heterocyclic Chemistry is the definitive serial within the area―one of significant value to natural chemists, polymer chemists and plenty of organic scientists. Written through confirmed experts within the box, the great studies mix descriptive chemistry and mechanistic perception and yield an realizing of ways the chemistry drives the properties.

    • One of serious significance to natural chemists, polymer chemists and lots of organic scientists
    • Written via tested specialists within the box, the excellent studies mix descriptive chemistry and mechanistic perception and yield an figuring out of the way the chemistry drives the properties

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T. Wang et al. reported the synthesis of several coumarin derivatives via Pechmann-type reaction and then linked them with a cyclopentanon Scheme 46 38 Majid M. Heravi et al. Scheme 46 Continued Pechmann Reaction in the Synthesis of Coumarin Derivatives 39 Scheme 47 Scheme 48 derivative 102 to give 103 with excellent photon-absorbing properties (Scheme 48) (07DP104). Since photophysical properties of fluorochromes are directly influenced by their chemical structure, J. A. Key et al. obtained a strategy for the conversion of a fluorophore-attached alkyne to a triazole through a copper-catalyzed Sharpless–Meldal reaction.

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A series of 36 Majid M. Heravi et al. Scheme 45 novel fluorinated 7-hydroxycoumarins 9, two fluorinated fluorescent dyes, 6,8-difluoro-7-hydroxy-4-methylcoumarin (R1, R2 = F, R3 = H, R4 = CH3 and R5 = H), and 3-carboxy-6,8-difluoro-7-hydroxycoumarin (R1, R2 = F and R3, R4 = H and R5 = CO2H), have been synthesized via Pechmann reaction and proven to have exceptional photophysical properties (Scheme 47) (98BMC3107). T. Wang et al. reported the synthesis of several coumarin derivatives via Pechmann-type reaction and then linked them with a cyclopentanon Scheme 46 38 Majid M.

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