By H. W. Doelle
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7, 407. Malhotra, O. , and Bernhard, S. A. (1968). Spectrophotometric identification of an active site-specific acyl glyceraldehyde 3-phosphate dehydrogenase. The regulation of its kinetics and equilibrium properties by coenzymes. J. Biol. Chem. 243, 1243. McCormick, D. , Koster, J. , and Veeger, C. (1967). On the mechanism of photochemical reactions of F A D and FAD-dependent flavoproteins. European J. Biochem. 2, 387. Welch, W. , Irwin, C. , and Hines, R. H. (1968). Observations on the monovalent cation requirements of formyltetrahydrofolate synthetase.
Acetyl CoA, can be formed in cells without the intervention of ATP; in anaerobic glycolysis, probably a very primitive process of energy production, it serves as a precursor of ATP. ENZYMES 39 On these grounds the CoA derivatives could possibly represent the evolutionary ancestors of ATP. Acyl-Group Carriers. Recent studies of intermediary metabolism of fats and carbohydrates drew attention to the acyl-group transfer, particularly by carriers containing thiol groups, with which they form thiol esters.
Biochem. (Tokyo) 61, 309. 5. Bullock, M. , Brockman, J. , Patterson, E. , Pierce, J. , and Stockstadt, E. L. R. (1952). Synthesis of compounds in the thioctic acid series. / . Am. Chem. Soc. 74, 3455. 6. Clark, W. M. (1960). " Williams & Wilkins, Baltimore, Maryland. 7. Dawes, E. A. (1963). " Livingstone, Edinburgh and London. 8. , and Webb, E. C. (1964). "Enzymes," 2nd ed. Longmans, Green, New York. 9. Glasstone, S. (1954). "An Introduction to Electrochemistry," 6th printing. Van Nostrand, Princeton, New Jersey.